2006 e350
#2
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2002 to 2009 is W211, so this is not the right forum. However, my advise would be to be look for a facelift model (i.e. 2007 or newer). The early W211s had quality issues and Mercedes made over 3000 changes (If i recall correctly) to the 2007 model to address these quality issues.
#3
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2008 E350 4Matic, 2011 E350 4matic
Not only that, but all 2006 had balance shaft problems which didn't get corrected til sometime in 2007 so 2008-2009 is safer. Also 2006 had the SBC brakes which they got rid of in 2007+.